Product ID:H1482U, ANCAMINE 1482
MSDS Date:10/01/1991
FSC:8040
NIIN:00N028761
MSDS Number: BNBKB

PACIFIC ANCHOR CHEMICAL

7201 HAMILTON BLVD
ALLENTOWN, PA 18195-1501
US

Emergency Phone: 800-523-9374;800-322-9092

Info Phone: 215-481-6933

Cage: OEMW2

PACIFIC ANCHOR CHEMICAL CORP

CUMBERLAND, RI 02864 US

Telephone: 213-264-0311;800-424-9300(CHEMTREC)

Cage: OEMW2

ANILINE, 4,4'-METHYLENEDI-(METHYLENE DIANILINE, 4,4'-)

CAS: 101-77-9

RTECS: BY5425000

Fraction By Weight: <35-60%

ACGIH TLV: 0.1 PPM,S

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

M-PHENYLENEDIAMINE; (BENZENEDIAMINE, 1,3-)

CAS: 108-45-2

RTECS: SS7700000

Fraction By Weight: <35-60%

OSHA PEL 0.1 MG/M3,S

ACGIH TLV: 0.1 MG/M3,S

WORK PLACE. PROMPTLY REMOVE CLOTHING THAT

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:CONTACT WITH EYES CAUSES
IRRITATION, REDNESS AND DISCOMFORT WHICH IS TRANSIENT. CONTACT WITH
SKIN CAUSES MILD IRRITATION AND DISCOMFORT. PRODUCT IS ABSORBED
THROUGH THE SKIN AND MAY CAUSE NAUSEA , HEADACHE AND GENERAL
DISCOMFORT. INHALATION OF AEROSOL, MIST OR FOG MAY CAUSE HARM.(EFTS
OF OVEREXPOSURE)
Explanation of Carcinogenicity:4,4'-METHYLENE DIANILINE:GROUP 2B
(IARC); GROUP 2 (NTP).
Effects of Overexposure:HLTH HAZ:CHRONIC:REPEATED AND/OR PROLONGED
CONTACT WITH SKIN MAY CAUSE PRIMARY SKIN IRRITATION & DERM.
RPTD/PRLNGD EXPOS MAY RSLT IN LIVER DISORDERS (SUCH AS JAUNDICE OR
ENLARGEMENT), ADVERSE SKIN EFT S (SUCH AS DEFAT, RASH, IRRIT OR
CORROSION).
Medical Cond Aggravated by Exposure:LIVER DISORDERS.

First Aid:EYE:HOLD EYELIDS APART & IMMED FLUSH W/ PLENTY OF WATER FOR
AT LEAST 15 MINS. CALL MD. SKIN:WASH W/SOAP & WATER. REMOVE CONTAM
CLTHG & SHOES. WASH BEFORE REUSE. DESTROY CONTAM LEATHER APPAREL.
CALL MD . INHAL:MOVE TO FRESH AIR & CALL MD. KEEP PATIENT QUIET &
START O2 THROUGH SUITABLE EQUIP. INGEST:CALL MD IMMED. INDUCE VOMIT
OR REMOVE STOMACH CONTENTS BY GASTRIC SUCTION ONLY AS DIRECTED
(SUPDAT)

Flash Point Method:PMCC
Flash Point:196F,91C
Extinguishing Media:IGNITION WILL GIVE RISE TO A CLASS B FIRE. IN CASE
OF FIRE USE SAND, EARTH, DRY CHEMICAL, FOAM, OR CO2.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. USE WATER SPRAY TO REDUCE VAPS. IF WATER POLLUTION OCCURS, NOTIFY
APPROP AUTH. CNTN RUNOFF WATER (SUPDAT)
Unusual Fire/Explosion Hazard:MAY GENERATE TOXIC, IRRITATING OR
FLAMMABLE COMBUSTION PRODUCTS; MAY GENERATE CO GAS; MAY GENERATE
TOXIC NOX GASES.

Spill Release Procedures:IF RECOVERY IS NOT FEASIBLE, ADMIX W/DRY SOIL,
SAND/NON-REACTIVE ABSORBENT & PLACE IN CNTNR/DUMPSTER PENDING DISP.
PLACE IN METAL CNTNRS FOR RECOVERY/DISP. REMOVE FROM SPILL
LOCATION. AVOID INHAL OF V APS. USE RESP PROT. WASH CONTAM PROPERTY
(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:AVOID STORAGE FOR LONG PERIODS & IN
LGE QTYS. KEEP IN COOL, DRY VENT STOR & IN CLSD CNTNRS. PROTECT
FROM EXPOS TO LIGHT. HNDL IN WELL VENT WORKSPACE.
Other Precautions:AVOID CONTACT WITH SKIN OR EYES. ADHERE TO WORK
PRACTICE RULES ESTABLISHED BY GOVERNMENT REGULATIONS. AVOID SKIN
CONTACT. WEAR PROT CLTHG. AVOID CONTAM OF GROUND SURF WATERS.
POTNTL FOR CO &/OR NOX GE NERATION IF FIRE MUST BE RECOGNIZED.

Respiratory Protection:NOT REQUIRED UNDER NORMAL USE CONDITIONS. FOR
EMERGENCY SITUATIONS USE NIOSH/MSHA APPROVED SCBA WITH PRESSURE
DEMAND MODE.
Ventilation:ADEQUATE GENERAL AND LOCAL EXHAUST. MAINTAIN AIR
CONCENTRATIONS IN WORK SPACES.
Protective Gloves:IMPERMIABLE GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE BATH AND SAFETY SHOWER.
Work Hygienic Practices:WASH AT END OF WORKSHIFT & BEFORE EATING, SMKNG
OR USING TOILET. CHANGE WORK CLTHG DAILY BEFORE LEAVING (ING 3)
Supplemental Safety and Health
FIRE FIGHT PROC:IN DIKES. PVNT STREAM CONTAM. KEEP CNTNRS COOL W/WATER
SPRAY. AVOID SKIN CONTACT. FIRST AID PROC: BY MD. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. SPILL PROC: (E.G.,
AUTOM OBILES) QUICKLY BEFORE MATL DRIES. CLEAN-UP PERS MUST BE
EQUIPPED W/SCBA AND BUTYL RUBBER PROTECTIVE CLOTHING.

HCC:V4
Boiling Pt:B.P. Text:DECOMPOSES
Spec Gravity:1.16 @ 77F
Solubility in Water:LIMITED
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS (I.E., PERCHLORATES, NITRATES, ETC.); EPOXY RESINS
UNDER CONTROLLED CONDITIONS.
Stability Condition to Avoid:NO DATA.
Hazardous Decomposition Products:CO, CO2, NOX IN A FIRE.

Waste Disposal Methods:DILUTE WITH ORGANIC SOLVENT AND INCINERATE USING
EFFLUENT GAS SCRUBBER. COMPLY WITH ALL FEDERAL, STATE AND LOCAL
REGULATIONS.

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assume responsibility for the suitability of this information to their
particular situation.